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Recent advances in transition metal-catalyzed N-atom transfer reactions of azides

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Title: Recent advances in transition metal-catalyzed N-atom transfer reactions of azides
Author(s): Driver, Tom G.
Subject(s): nitrenoid Transition metal-catalyzed N-atom transfer reactions
Abstract: Transition metal-catalyzed N-atom transfer reactions of azides provide efficient ways to construct new carbon–nitrogen and sulfur–nitrogen bonds. These reactions are inherently green: no additive besides catalyst is needed to form the nitrenoid reactive intermediate, and the by-product of the reaction is environmentally benign N2 gas. As such, azides can be useful precursors for transition metal-catalyzed N-atom transfer to sulfides, olefins and C–H bonds. These methods offer competitive selectivities and comparable substrate scope as alternative processes to generate metal nitrenoids.
Issue Date: 2010-09-07
Publisher: Royal Society of Chemistry
Citation Info: Driver, T. G. 2010. Recent advances in transition metal-catalyzed N-atom transfer reactions of azides. Organic and Biomolecular Chemistry, 8(17): 3831-3846. DOI: 10.1039/c005219c
Type: Article
Description: The definitive version is available through Royal Society of Chemistry at DOI: 10.1039/c005219c
URI: http://hdl.handle.net/10027/7901
ISSN: 7-0539
Sponsor: The National Institutes of Health NIGMS (R01GM084945), Petroleum Research Fund administered by the American Chemical Society (46850-G1), and the University of Illinois at Chicago are acknowledged for their generous support of our research program.
Date Available in INDIGO: 2011-08-31
 

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