%0 Thesis %A Kuznetsov, Alexey %D 2014 %T New Advances in the Synthesis of Siloles and N-Heterocycles %U https://indigo.uic.edu/articles/thesis/New_Advances_in_the_Synthesis_of_Siloles_and_N-Heterocycles/10833509 %2 https://indigo.uic.edu/ndownloader/files/19341431 %K Dihydrobenzosiloles %K C-H Silylation %K Furan Recyclization %K Indoles %K Diazocompounds %K 1,2,3-Triazolines. %X This thesis describes the development of novel transition-metal-catalyzed processes for the synthesis of dihydrobenzosiloles and fused heteroaromatic dihydrosiloles starting from aromatic- and heteroaromatic styrenes. It also includes the development of a Brønsted acid-catalyzed protocol for the synthesis of indoles via recyclization reaction of ortho-aminobenzyl alcohols and furans, as well as the development of a new reactivity mode of diazocompounds: 1,3-aminoalkylation reaction of beta-amino-alpha-diazoesters towards triazolines. %I University of Illinois at Chicago