10027/18812
Ke Sun
Ke
Sun
Transition-Metal Catalyzed C-H Bond Amination from Aryl Azide
University of Illinois at Chicago
2014
Transition metal
Benzylic C–H amination
Aliphatic C–H amination
Aryl azide
Rh(II) carboxylate
Indole
Indoline
Migration
2014-06-20 00:00:00
Thesis
https://indigo.uic.edu/articles/thesis/Transition-Metal_Catalyzed_C-H_Bond_Amination_from_Aryl_Azide/10860434
This thesis describes transition metal catalyzed benzylic and aliphatic C–H amination reaction by employing aryl azides as the nitrogen source, with the generation of indoline. Additionly, Rh(II) carboxylate promoting disubtituted indole formation from β, β-disubstituted styryl azide is discussed afterwards.