University of Illinois at Chicago
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Transition-Metal Catalyzed C-H Bond Amination from Aryl Azide

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thesis
posted on 2014-06-20, 00:00 authored by Ke Sun
This thesis describes transition metal catalyzed benzylic and aliphatic C–H amination reaction by employing aryl azides as the nitrogen source, with the generation of indoline. Additionly, Rh(II) carboxylate promoting disubtituted indole formation from β, β-disubstituted styryl azide is discussed afterwards.

History

Advisor

Dirver, Tom

Department

Chemistry

Degree Grantor

University of Illinois at Chicago

Degree Level

  • Doctoral

Committee Member

Eichman, Chad Anderson, Laura Wardrop, Duncan Wink, Donald

Submitted date

2014-05

Language

  • en

Issue date

2014-06-20

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    Keywords

    Transition metalBenzylic C–H aminationAliphatic C–H aminationAryl azideRh(II) carboxylateIndoleIndolineMigration

    Licence

    In Copyright

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