Formal C–H Amination of Cyclopropenes

A novel C(sp(3))-H amination of trimethylsilyl-substituted cyclopropenes is described. This C-H amination proceeds via a tandem regioselective ene reaction between cyclopropenes and azodicarboxylate to generate a hydrazodicarboxylate intermediate followed by its site-selective allylic transposition.

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