Formal C–H Amination of Cyclopropenes
journal contributionposted on 05.12.2013 by Chunrui Sun, Jingwei Li, Daesung Lee, Genping Huang, Yuanzhi Xia
Any type of content formally published in an academic journal, usually following a peer-review process.
A novel C(sp(3))-H amination of trimethylsilyl-substituted cyclopropenes is described. This C-H amination proceeds via a tandem regioselective ene reaction between cyclopropenes and azodicarboxylate to generate a hydrazodicarboxylate intermediate followed by its site-selective allylic transposition.