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Formal C–H Amination of Cyclopropenes

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posted on 05.12.2013 by Chunrui Sun, Jingwei Li, Daesung Lee, Genping Huang, Yuanzhi Xia
A novel C(sp(3))-H amination of trimethylsilyl-substituted cyclopropenes is described. This C-H amination proceeds via a tandem regioselective ene reaction between cyclopropenes and azodicarboxylate to generate a hydrazodicarboxylate intermediate followed by its site-selective allylic transposition.

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Post print version of article may differ from published version. The definitive version is available through Royal Society of Chemistry at DOI:10.1039/c2cc35329f

Citation

Sun C, Li J, Lee D, Huang G, Xia Y. Formal C-H amination of cyclopropenes. Chemical Communications (Camb). 2012 Nov 18;48(89):10990-2. doi: 10.1039/c2cc35329f.

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Royal Society of Chemistry

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en_US

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1364-548X

Issue date

01/11/2012

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