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Synthesis of High-Quality AgSbSe2 and AgBiSe2 Nanocrystals with Antimony and Bismuth Silylamide Reagents

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journal contribution
posted on 29.06.2018, 00:00 by A Das, B Hsu, A Shamirian, Z Yang, PT Snee
Silver dimetal chalcogenides (Ag-V-VI2) are ternary semiconductors that have potential alternative energy applications due to their optimal band gaps and large extinction coefficients. The synthesis of these materials is challenging due to the lack of effective pnictide precursors. We report the use of tris[N,N-bis(trimethylsily)amido]antimony (Sb [N(SiMe3)(2)](3)) and tris [N,N-bis (trimethylsilyl) amido]bis-muth (Bi[(N(SiMe3)(2)](3)) to synthesize nanocrystalline AgSbSe2 and AgBiSe2 quantum dots. The use of these reagents results in the creation of high quality nanomaterials with good crystallinity and narrow size distributions. Furthermore, electrical measurements on monolithic pellets of processed AgSbSe2 and AgBiSe2 nanomaterials demonstrate linear current voltage behavior at room temperature, which indicates potential for use in electrical applications.

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Publisher Statement

"This is a copy of an article published in the CHEMISTRY OF MATERIALS © 2017 AMER CHEMICAL SOC "

Publisher

American Chemical Society

Language

en_US

issn

0897-4756

Issue date

23/05/2017

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