posted on 2016-03-29, 00:00authored byU. Chatterjee, J. Zhao, M. Iavarone, R. Di Capua, J.P. Castellan, G. Karapetrov
A charge-density wave (CDW) state has a broken symmetry described by a complex order parameter with an amplitude and a phase. The conventional view, based on clean, weak-coupling systems, is that a finite amplitude and long-range phase coherence set in simultaneously at the CDW transition temperature T(cdw). Here we investigate, using photoemission, X-ray scattering and scanning tunnelling microscopy, the canonical CDW compound 2H-NbSe2 intercalated with Mn and Co, and show that the conventional view is untenable. We find that, either at high temperature or at large intercalation, CDW order becomes short-ranged with a well-defined amplitude, which has impacts on the electronic dispersion, giving rise to an energy gap. The phase transition at T(cdw) marks the onset of long-range order with global phase coherence, leading to sharp electronic excitations. Our observations emphasize the importance of phase fluctuations in strongly coupled CDW systems and provide insights into the significance of phase incoherence in 'pseudogap' states.
Funding
Work at Argonne (U.C., J.Z., J.P.C., C.D.M., M.G.K., H.C., J.P.C.R., F.W., J.C.C, R.O.,
M.R.N., S.R.) was supported by the Materials Science and Engineering Division, Basic
Energy Sciences, Office of Science, U.S. Department of Energy. Work at Temple University
(M.I) and Drexel University (G.K.) was supported as part of the Center for the
Computational Design of Functional Layered Materials, an Energy Frontier Research
Center funded by the U.S. DOE, BES under Award DE-SC0012575. J.v.W. acknowledges
support from a VIDI grant financed by the Netherlands Organization for Scientific
Research (NWO). M.R. was supported by the DOE-BES grant DE-SC0005035. N.T. was
supported by the U.S. DOE, Office of Science, Grant DE-FG02-07ER46423. The Synchrotron
Radiation Center is supported by the University of Wisconsin, Madison.
Synchrotron X-ray scattering experiments were carried out at the Advanced Photon
Source, which is supported by the DOE, Office of Science, BES. We thank Ming Shi for
his support with the experiments at the Swiss Light Source, Paul Scherrer Institut,
Switzerland, and D. Robinson and K. Attenkofer for their support with the XRD measurements
at the Advanced Photon Source, Argonne National Laboratory.