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New Advances in the Synthesis of Siloles and N-Heterocycles

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thesis
posted on 28.10.2014, 00:00 by Alexey Kuznetsov
This thesis describes the development of novel transition-metal-catalyzed processes for the synthesis of dihydrobenzosiloles and fused heteroaromatic dihydrosiloles starting from aromatic- and heteroaromatic styrenes. It also includes the development of a Brønsted acid-catalyzed protocol for the synthesis of indoles via recyclization reaction of ortho-aminobenzyl alcohols and furans, as well as the development of a new reactivity mode of diazocompounds: 1,3-aminoalkylation reaction of beta-amino-alpha-diazoesters towards triazolines.

History

Advisor

Gevorgyan, Vladimir

Department

Chemistry

Degree Grantor

University of Illinois at Chicago

Degree Level

Doctoral

Committee Member

Wardrop, Duncan Lee, Daesung Mohr, Justin Brusik, Karol

Submitted date

2014-08

Language

en

Issue date

28/10/2014

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