Kuznetsov_Alexey.pdf (17.39 MB)
New Advances in the Synthesis of Siloles and N-Heterocycles
thesis
posted on 2014-10-28, 00:00 authored by Alexey KuznetsovThis thesis describes the development of novel transition-metal-catalyzed processes for the synthesis of dihydrobenzosiloles and fused heteroaromatic dihydrosiloles starting from aromatic- and heteroaromatic styrenes. It also includes the development of a Brønsted acid-catalyzed protocol for the synthesis of indoles via recyclization reaction of ortho-aminobenzyl alcohols and furans, as well as the development of a new reactivity mode of diazocompounds: 1,3-aminoalkylation reaction of beta-amino-alpha-diazoesters towards triazolines.
History
Advisor
Gevorgyan, VladimirDepartment
ChemistryDegree Grantor
University of Illinois at ChicagoDegree Level
- Doctoral
Committee Member
Wardrop, Duncan Lee, Daesung Mohr, Justin Brusik, KarolSubmitted date
2014-08Language
- en
Issue date
2014-10-28Usage metrics
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